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sulfure d arsenic.
sulfur in influencing arsenic uptake and release from solu-tion and the complex interplay among adsorption and pre-cipitation processes, changes in oxidation states and min-eral stabilities, and the rates of these processes as mediated by microbial activities in surface and subsurface environ-ments (O'Day et al. 2004; Oremland and Stolz 2005).
Differentially regulated miRNAs under low sulfur and arsenic stress. Identification of miRNAs in response to As and sulfur deficiency could be very helpful to decipher the regulatory pathway involving specific miRNAs in these stresses. Thus, to identify miRNAs with modulated expression in response to As stress and sulfur limitation …
Sulfide minerals consist of one or more metals combined with sulfur; sulfarsenides contain arsenic replacing some of the sulfur. Sulfides are generally opaque and exhibit distinguishing colours and streaks. ( Streak is the colour of a mineral's powder.) The nonopaque varieties (e.g., cinnabar, realgar, and orpiment) possess high refractive ...
Sublimed arsenic vapour readily burns in air to form arsenious oxide. The free element is essentially unaffected by water, bases, or nonoxidizing acids, but it can be oxidized by nitric acid to the +5 state. Halogens attack arsenic, as does sulfur, and the element will combine directly with many metals forming arsenides. Analytical chemistry
The average arsenic to sulfur ratio of the fine nodules was much lower than the stoichiometric value, suggesting the formation of secondary phases enriched in sulfur. The presence of elemental sulfur in the leaching residue was further confirmed by XRD analysis of the leaching residue (Fig. 7-A). It seems that the arsenic-deficient layer and ...
Sulfur and arsenic often coexist in the environment and share similar microbial redox transformations. We examined the effects of sulfide on aerobic arsenite oxidation in alkaline lake water samples and in laboratory enrichment cultures. Significant arsenite oxidation occurred only in treatments with bacteria present, and production of arsenate was greatly …
Sulfur-driven arsenite oxidation and microbial thioarsenate transformation may be important biogeochemical processes in the arsenic cycle of the study site (Mono Lake, CA, USA) and other alkaline environments as well. Sulfur and arsenic often coexist in the environment and share similar microbial redox transformations. We examined the effects of sulfide on …
Arsenic is a naturally occurring element widely distributed in the earth's crust. In the environment, arsenic is combined with oxygen, chlorine, and sulfur to form inorganic arsenic compounds. Arsenic in animals and plants combines with carbon and hydrogen to form organic arsenic compounds. Inorganic arsenic compounds are mainly used to ...
The measurement of sulfur isotopes in sulfur-containing arsenides, as well as arsenic and mercury sulfides, by EA/IRMS can be problematic. Improper storage, handling, and analytical protocols for the analysis of arsenic- and mercury-containing samples can lead to potential health hazards at the workplace and mass spectrometric …
The role of sulfur cycling in arsenic behavior under reducing conditions is not well-understood in previous investigations. This study provides observations of sulfur and oxygen isotope fractionation in sulfate and evaluation of sulfur cycling-related biogeochemical processes controlling dissolved arsenic groundwater concentrations …
The biogeochemical cycling of arsenic (As) and antimony (Sb) is coupled with sulfur (S). Biogenic sulfide from microbial sulfate reduction under anaerobic conditions may enhance the release of coexisting As and Sb through the formation of labile thioarsenate (As V-S) and thioantimonate (Sb V-S).To understand the competition between As and Sb for …
The reduction of sulfur may induce processes that decrease As solubility, but its impact on rice grain As species remains u … Sulfur amendments to soil decrease inorganic arsenic accumulation in rice grain under flooded and nonflooded conditions: Insights from temporal dynamics of porewater chemistry and solid-phase arsenic solubility
Arsenic has a particular affinity for sulfur and is often found joined to sulfur in ores – mixtures of minerals that are mined for profitable materials such as silver or copper. The common ore arsenopyrite, a rusty red rock, is a combination of arsenic with sulfur and iron. This ore, known since the Greeks of Aristotle's time, is an ...
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